Metal-Nonmetal Transition of Liquid Tl&ndash;As<SUB>2</SUB>Se<SUB>3</SUB> System

A ug 2 00 7 Nature of the metal - nonmetal transition in metal - ammonia solutions . I .

Gennady N. Chuev, Pascal Quémerais, and Jason Crain (1) Institute of Theoretical and Experimental Biophysics, Russian Academy of Science, Pushchino, Moscow Region, 142290, Russia (2)Institut Néel, CNRS, BP 166, 38042 Grenoble Cedex 9, France (3) School of Physics, The University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, United Kingdom (4) National Physical Laboratory, Hampton Road, Teddin...

The equation of state and nonmetal-metal transition of benzene under shock compression

Abstract We employ quantum molecular dynamic simulations to investigate the behavior of benzene under shock conditions. The principal Hugoniot derived from the equation of state is determined. We compare our firs-principles results with available experimental data and provide predictions of chemical reactions for shocked benzene. The decomposition of benzene is found under the pressure of 11 GP...

Core-hole screening as a probe for a metal-to-nonmetal transition in lead clusters.

Metal clusters serve as model systems to study basic problems of electronic correlation. Vacuum ultraviolet light from the free-electron laser FLASH ionizes 5d electrons from mass-separated negatively charged clusters, thus transiently leading to core-ionized neutral systems. Shielding of the core hole affects the electron binding energy. From the strong deviation from expectations of the metal...

The influence of both coordination number and lattice constant on the nonmetal to metal transition

Medium-range fluctuations accompanying the metal-nonmetal transition in expanded fluid hg.

We have carried out small angle x-ray scattering experiments of expanded fluid Hg in the metal-nonmetal (M-NM) transition region around 9.0 g cm(-3). Increase of small angle scattering intensity following the Ornstein-Zernike equation is clearly observed in the M-NM transition region as well as near the liquid-vapor critical point at 5.8 g cm(-3). The short-range correlation length, R, becomes ...